isolation and structural elucidation of the first known c-homoprotoberberine
نویسندگان
چکیده
a novel c-homoprotoberberine alkaloid, hediamine (2), has been isolated from the roots of berberis actinucantha (berberidaceae). conclusive proof for the structure of hediamine was obtained by its comparison with the isomeric lactam (4), by chemical transformation, and by means of spectroscopic techniques (uv, ir, ms, nmr).
منابع مشابه
ISOLATION AND STRUCTURAL ELUCIDATION OF THE FIRST KNOWN C-HOMOPROTOBERBERINE
A novel C-homoprotoberberine alkaloid, Hediamine (2), has been isolated from the roots of Berberis actinucantha (Berberidaceae). Conclusive proof for the structure of hediamine was obtained by its comparison with the isomeric lactam (4), by chemical transformation, and by means of spectroscopic techniques (UV, IR, MS, NMR).
متن کاملFermentation, Isolation, Structural Elucidation and Biological Activities
A fermentation broth of an unidentified fungus (N983-46) was found to produce DNAgyrase inhibitors, CJ-12,371 (1) and CJ-12,372 (2). Following isolation by solvent extraction and silica gel and ODS(reverse phase) chromatographies, the structures were determined to be novel spiro-ketal compounds with S-connguration at position C-l. CJ-12,371 and CJ-12,372 inhibit both DNA supercoiling and relaxa...
متن کاملefl students gender and socioeconomic status: the use of politeness strategies in the first and second languages
within the components of communicative competence, a special emphasis is put on the “rules of politeness,” specifically the politeness strategies (brown and levinson, 1978) that speakers deploy when performing the request speech act. this is because the degree of imposition that making a request places upon one’s interlocutor(s) has been seen to be influenced by several factors among which, as ...
Isolation and structural elucidation of an antioxidative agent, naphterpin.
Active oxygen species cause a variety of diseases such as inflammation, autoimmune disease, diabetes, rheumatism, cardiovascular diseases and cancer-initiation1>2). Thus, it could be expected that antioxidative agents may prevent these diseases. We have screened antioxidants of microbial origin by employing the Yagi method after minor modification using rat liver microsome free from vitamin E3)...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
journal of sciences islamic republic of iranجلد ۷، شماره ۳، صفحات ۰-۰
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023